JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000162
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000162
Regist Date
 2012/06/21 14:37:28
REACTANT
MOLECULE ID
 JCGG-COM0000032
Reactant Type
 activator
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000048 (Reaction Tree)
Skeleton
JCGG-STR032525
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000197
Reactant Type
 aryl compound
Mol
 1 equiv.
PRODUCT
MOLECULE ID
 JCGG-COM0000198 (Reaction Tree)
Skeleton
JCGG-STR031569
Product Type
 beta
Yield
 74%(alpha/beta=67/33)
MOLECULE ID
 JCGG-COM0000199 (Reaction Tree)
Skeleton
JCGG-STR032525
Product Type
 alpha
Yield
 74%(alpha/beta=67/33)
REACTION DETAIL
Reaction Temp
 room temp
Solvent
 benzene
Catalyst
 activator
AgClO4
Reaction Type
 aryl glycosidation
Comment
 The reaction time could not be found. (considered to be short)
MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by the measurement of 1H NMR.
REFERENCE
Reference Id
 REF-0000-000010
Source
 Bulletin of the Chemical Society of Japan Vol. 67 (1994) , No. 5 pp.1488-1491
Doi
 10.1246/bcsj.67.1488
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)