JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000155
Submitter
The Noguchi Institute
Reaction ID
R-0000-000155
Regist Date
2012/08/08 13:53:11
REACTANT
MOLECULE ID
JCGG-COM0000185
Reactant Type
phenols
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000032
Reactant Type
activator
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000048 (Reaction Tree)
Skeleton
JCGG-STR032525
Mol
1 equiv.
PRODUCT
MOLECULE ID
JCGG-COM0000016 (Reaction Tree)
Skeleton
JCGG-STR032525
Product Type
alpha
Yield
75%(alpha/beta=58/42)
MOLECULE ID
JCGG-COM0000015 (Reaction Tree)
Skeleton
JCGG-STR031569
Product Type
beta
Yield
75%(alpha/beta=58/42)
REACTION DETAIL
Reaction Time
overnight
Reaction Temp
room temp
Solvent
benzene
Catalyst
AgClO4
Reaction Type
aryl glycosidation
Comment
MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
Keywords: glucopyranosyl dimethylphosphinothioate, phenolic compound, aryl glycoside, glycosylphenol, silver perchlorate, AgClO4
REFERENCE
Reference Id
REF-0000-000010
Source
Bulletin of the Chemical Society of Japan Vol. 67 (1994) , No. 5 pp.1488-1491
Doi
10.1246/bcsj.67.1488

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)