JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000122
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000122
Regist Date
 2012/06/21 14:20:15
REACTANT
MOLECULE ID
 JCGG-COM0000136 (Reaction Tree)
Reactant Type
 donor
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000031
Reactant Type
 Acceptor
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000084
Reactant Type
 Activator
Mol
 0.5 equiv.
MOLECULE ID
 JCGG-COM0000035
Reactant Type
 Activator
Mol
 0.05 equiv.
PRODUCT
MOLECULE ID
 JCGG-COM0000137 (Reaction Tree)
Product Type
 alpha
Yield
 52%(alpha/beta=61/39)
MOLECULE ID
 JCGG-COM0000138 (Reaction Tree)
Product Type
 beta
Yield
 52%(alpha/beta=61/39)
REACTION DETAIL
Solvent
 PhH
Catalyst
 Activator
Comment
 MS 4A was included in the solvent.
The reaction temperature could not be found.
The reaction time could not be found.
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by HPLC and 1H NMR.
REFERENCE
Reference Id
 REF-0000-000006
Source
 Chemistry Letters Vol. 22 (1993), No. 2 p.343
Doi
 10.1246/cl.1993.343
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)