JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000112
Submitter
The Noguchi Institute
Reaction ID
R-0000-000112
Regist Date
2012/06/21 14:19:43
REACTANT
MOLECULE ID
JCGG-COM0000122 (Reaction Tree)
Skeleton
JCGG-STR025316
Reactant Type
Glycosyl donor
Mol
1.3 equiv.
MOLECULE ID
JCGG-COM0000068 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
Substrate
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000084
Reactant Type
Activator
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000035
Reactant Type
Activator
Mol
0.6 equiv.
PRODUCT
MOLECULE ID
JCGG-COM0000133 (Reaction Tree)
Product Type
beta
Yield
68%(alpha/beta=0/100)
REACTION DETAIL
Reaction Time
16 hours
Reaction Temp
room temp
Solvent
PhH
Catalyst
Activator
Comment
MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
Only beta was obtained.
The alpha/beta ratio was determined by 13C NMR.
REFERENCE
Reference Id
REF-0000-000005
Source
Chemistry Letters, Vol. 18 (1989), No. 1 p.69
Doi
10.1246/cl.1989.69

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)