Reaction:JCGG-RAC0000059

JCGG ID		JCGG-RAC0000059
Submitter		The Noguchi Institute
Reaction ID		R-0000-000059
Regist Date		2012/06/21 13:01:06
REACTANT
MOLECULE ID		JCGG-COM0000085 (Reaction Tree)
	Reactant Type	Starting suger derivative
	Mol	0.2 mmol (1 equiv.)
MOLECULE ID		JCGG-COM0000028
	Reactant Type	Bu(n)Li
	Mol	0.24 mmol (1.1 equiv.)
MOLECULE ID		JCGG-COM0000086
	Reactant Type	Ac2O
	Mol	6 equiv.
	Volume	0.3 mL
PRODUCT
MOLECULE ID		JCGG-COM0000087 (Reaction Tree)
	Yield	80%
REACTION DETAIL
Reaction Time		1 hour
		1 hour
Reaction Temp		-78 to -30 degree C
		-30 to 0 degree C
Solvent		THF
		THF
Comment		The addition of Bu(n)Li
		The addition of Ac2O
		Method A in Scheme 5
COMMENT
The PMID could not be found.
There are two phases in this reaction.
The productivity will decrease to 69% if the reaction is performed at -78 degree C.
REFERENCE
Reference Id		REF-0000-000004
	Source	Tetrahedron 62 (2006) 10383‐10392
	Doi	10.1016/j.tet.2006.08.059