JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000033
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000033
Regist Date
 2012/06/21 12:26:20
REACTANT
MOLECULE ID
 JCGG-COM0000030 (Reaction Tree)
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000031
Reactant Type
 ROH
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000035
Reactant Type
 Activator
Mol
 0.1 equiv.
PRODUCT
MOLECULE ID
 JCGG-COM0000033 (Reaction Tree)
Product Type
 alpha
Yield
 35%(alpha/beta=2/1)
MOLECULE ID
 JCGG-COM0000034 (Reaction Tree)
Product Type
 beta
Yield
 35%(alpha/beta=2/1)
REACTION DETAIL
Reaction Time
 2 hours
Reaction Temp
 room temp
Solvent
 PhH
Catalyst
 Activator
Comment
 MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by 13C NMR spectroscopy.
The amount of the activator may be wrong.
REFERENCE
Reference Id
 REF-0000-000002
Source
 CHEMISTRY LETTERS, pp. 849-852, 1990
Doi
 10.1246/cl.1990.849
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)